On the cap replacement front, replacing caps is often an insurance policy, if one of the caps shorts, pop goes the tweeter, midrange, or worse. It is also possible that after the new caps “wear in” that it will improve sound quality and/or return the overall frequency response back to where it was designed to be, as you have mentioned cap values can change in 30 years. Highly unlikely inductors should be replaced, ones part of a well designed system (Polk) probably will not be improved upon dramatically. As a comment, a few years ago I replaced the caps in one of my AR-LST’s ( built ~1973) as a preventive measure, was a very tough job (well, for me) based on the way the x-over board was located… got busy, did not do the other. AR used high quality components, I was just afraid that one of the electrolytics would die while I was redlining my M1.5 during a party. If memory was correct, I used Solen’s for the mid, and a more esoteric cap for the tweets. Long story short, I think I would say that today, the speaker I changed the caps in is a little “brighter” than the one I didn’t, not that either can be criticized as being “dull”. I would not say there is a huge difference, but there is at least some difference. There was a big sprague that I missed on the schematic (~2500mfd) that was not replaced (no parts) as I had not done the proper research at the time.
On the active crossover front, another good active crossover is the TDM Design series, TDM CX-2, CX-3, CX-4 (stereo 2 way, 3 way, 4 way). They have been sold both as pro & consumer, Madisound sold them at one time as their “Sledgehammer” active crossovers. They have the usual 24db Linkwitz alignment. Pretty easy to find on ePay for a reasonable amount, I picked up my CX-4 for less than $80. In my case, am only using for stereo subwoofers, normally a CX-2 would fill the bill. Note that the vast majority of the units are pro-sound oriented, meaning the connections will be XLR etc, which you can use with home audio with simple cable converters, I happened to get one of the comparatively less common RCA jack versions.
If you decide to go the active route, you may want to keep in mind the existing crossover driver slopes of your speakers when shifting to an electronic crossover – many speakers used either 6db or 12db slopes because of the difficulty in designing a 24db slope in a passive (cap & coil) crossover. So it may sound a little different just because of the slope differences. You will also need to find a way to balance the relative volume of the tweeter section with midrange with woofer, etc – an equalizer with a RTA & mic (like above, I have a C-101) or some other PC RTA software.
Just replacing the caps with good quality replacements is probably the best place to start – JMO of course.
Joe